Method of making a proton exchange membrane using a gas diffusion electrode as a substrate

ABSTRACT

One embodiment includes a method comprising providing a first catalyst coated gas diffusion media layer, depositing a wet first proton exchange membrane layer over the first catalyst coated gas diffusion media layer to form a first proton exchange membrane layer; providing a second catalyst coated gas diffusion media layer; contacting the second catalyst coated gas diffusion media layer, or second proton exchange membrane layer, with the first proton exchange membrane layer; and hot pressing together the catalyst coated diffusion layers and proton exchange membrane layer(s).

TECHNICAL FIELD

The field to which the disclosure generally relates includes a membraneelectrode assembly (MEA) and, more particularly, an MEA for a protonexchange membrane fuel cell.

BACKGROUND

Hydrogen is a very attractive fuel because it is clean and can be usedto efficiently produce electricity in a fuel cell. The automotiveindustry expends significant resources in the development of hydrogenfuel cells as a source of power for vehicles. Such vehicles would bemore efficient and generate fewer emissions than today's vehiclesemploying internal combustion engines.

A hydrogen fuel cell is an electro-chemical device that includes ananode and a cathode with an electrolyte between the anode and thecathode. The anode receives hydrogen-rich gas or pure hydrogen and thecathode receives oxygen or air. The hydrogen gas is dissociated in theanode to generate free protons and electrons. The protons pass throughthe electrolyte to the cathode, where the protons react with the oxygenand the electrons in the cathode to generate water. The electrons fromthe anode are unable to pass through the electrolyte. Therefore, theelectrons are directed through a load to perform work before they aresent to the cathode. The work may be used, for example, to operate avehicle.

Proton exchange membrane fuel cells generally include a solid polymerelectrolyte proton conducting membrane, such as a perfluorosulfonic acidmembrane. The anode and the cathode typically include finely dividedcatalytic particles supported on carbon particles and mixed with anionomer and a solvent. The combination of the anode, cathode andmembrane define a membrane electrode assembly (MEA). The MEA may alsoinclude gas diffusion media, a porous layer that is necessary for gasand water transport through the MEA. The catalyst layer may be coated onthe diffusion media, for example the catalyst layer may be rolled orpainted or sprayed on the diffusion media as a slurry, and thencompressed. It is known in the art to sandwich the membrane between twopieces of the catalyst coated diffusion media with the catalyst sidesfacing the membrane, and then to hot-press to bond the catalyst coateddiffusion media to the membrane.

SUMMARY OF EXEMPLARY EMBODIMENTS OF THE INVENTION

One embodiment includes a method comprising providing a first catalystcoated gas diffusion media layer, depositing a wet first proton exchangemembrane layer over the first catalyst coated gas diffusion media layerto form a first proton exchange membrane layer; providing a secondcatalyst coated gas diffusion media layer; contacting the secondcatalyst coated gas diffusion media layer, or second proton exchangemembrane layer, with the first proton exchange membrane layer; and hotpressing together the catalyst coated diffusion layers and protonexchange membrane layer(s).

Other exemplary embodiments of the invention will become apparent fromthe detailed description provided hereinafter. It should be understoodthat the detailed description and specific examples, while indicatingexemplary embodiments of the invention, are intended for purposes ofillustration only and are not intended to limit the scope of theinvention.

BRIEF DESCRIPTION OF THE DRAWINGS

Exemplary embodiments of the invention will become more fully understoodfrom the detailed description and the accompanying drawings.

FIG. 1 illustrates a method according to one embodiment of theinvention;

FIG. 2 illustrates a method according to one embodiment of theinvention;

FIG. 3 illustrates a method according to one embodiment of theinvention;

FIG. 4A illustrates a method according to one embodiment of theinvention;

FIG. 4B illustrates a method according to one embodiment of theinvention;

FIG. 4C illustrates a method according to one embodiment of theinvention;

FIG. 5 is a cross-sectional view of a membrane electrode assembly,according to one embodiment of the invention;

FIG. 6 illustrates a method according to one embodiment of theinvention;

FIG. 7 is a cross-sectional view of a membrane electrode assembly,according to one embodiment of the invention.

DETAILED DESCRIPTION OF EXEMPLARY EMBODIMENTS

The following description of the embodiments is merely exemplary innature and is in no way intended to limit the invention, itsapplication, or uses.

In one embodiment of the invention, a method is provided by which aproton exchange membrane is made using a catalyst coated gas diffusionelectrode as a substrate.

In one embodiment of the invention, a first catalyst layer 10 is appliedto a first gas diffusion media layer 12 to form a first catalyst coatedgas diffusion media layer 16. The first catalyst layer 10 may includesuitable catalytic particles, for example, metals such as platinum,platinum alloys, and other catalysts known to those skilled in the fuelcell art. The first gas diffusion media layer 12 may be a conventionalfuel cell gas diffusion material such as nonwoven carbon fiber paper,woven carbon cloth, or carbon foam, for example. The applying of thecatalyst layer 10 may include any suitable method of applying, forexample, rolling, painting, or spraying. In another embodiment, as shownin FIG. 1, a first microporous layer 14 is applied to the first gasdiffusion media layer 12 and the first catalyst layer 10 is applied overthe first microporous layer 14 to form the first catalyst coated gasdiffusion media layer 16. The applying of the first microporous layer 14may include any suitable method of applying, for example, rolling orpainting. The microporous layer 14 may include particles and a binder.Suitable particles for the microporous layer 14 may include, but are notlimited to, graphitic, graphitized, or conductive carbon particles.Suitable binders for the microporous layer 14 may include at least oneof polytetrafluoroethylene (PTFE), polyvinylidenefluoride (PVDF),fluoroethylene propylene (FEP), or other organic or inorganichydrophobic materials.

As shown in FIG. 2, in one embodiment a first wet proton exchangemembrane layer is formed over the first catalyst coated gas diffusionmedia layer 16. The forming of the first wet proton exchange membranelayer may include any suitable technique, for example casting,laminating, imbibing, or spraying. The first wet proton exchangemembrane may include a support or reinforcing sheet, for example a sheetof porous layer, for example expanded polytetrafluoroethylene (ePTFE) orTeflon. In another embodiment, the first wet proton exchange membranemay include a support including one of a porous material less than 30 μmthick, a paper less than 30 μm thick, polyolefins, polyethylene,polypropylene, polyesters, polyphenylene sulfide, or polymers withcrystalline melting temperatures which do not dissolve in the coatingsolvents or dispersants used to imbibe an ionomer into the supportmaterial. The porous material or paper may be available from Crane andCo., Dalton, Mass. The polyethylene or polypropylene may be availablefrom DSM or Tonen Chemical Nasu Co., Ltd., Japan. In one embodiment, theforming comprises casting, wherein a reinforcing sheet is evenlydeposited over the catalyst layer 10 and an ionomer solution is appliedover the reinforcing sheet. The ionomer solution may be, but is notlimited to, an ionomer dispersion including Nafion 1000 (20 wt. %) in40-48 wt. % 1-propanol and 30-38 wt. % water. The ionomer solution mayinfiltrate or fill the pores of the reinforcing sheet. The ionomersolution may also penetrate at least one of the catalyst layer 10 andthe microporous layer 14. In one embodiment, the ionomer solution may beheated to flash off the solvents and provide a dried solid polymermembrane reinforced by the ePTFE.

In another embodiment, the forming of the first wet proton exchangemembrane comprises laminating, imbibing, or spraying, wherein thereinforcing sheet is immersed in the ionomer solution to form a wetmembrane, and then this wet reinforced membrane is evenly deposited overthe catalyst layer 10.

The first wet proton exchange membrane layer may be dried, for exampleunder low pressure, to form a first proton exchange membrane layer 18.

In another embodiment, a multilayer coating including the catalyst layer10 and the first proton exchange membrane layer 18 may be deposited overthe first gas diffusion media layer 12. In another embodiment, the wetfirst microporous layer 14 is applied to the first gas diffusion medialayer 12, dried, and sintered; the wet first catalyst layer 10 isapplied to the first microporous layer 14; the first wet proton exchangemembrane layer may be formed over the wet first catalyst layer 10; andall the layers may be dried simultaneously at the end of the process.The various methods described herein may eliminate the need for anadditional proton exchange membrane layer substrate, for examplepolyethylene and polypropylene polymer based films, typically used inthe manufacture and further processing of a proton exchange membranelayer. The various methods described herein are also an alternative toeliminate the need for a catalyst decal substrate, for example porousePTFE, or a non-porous substrate film for exampleethylene-tetrafluoroethylene (ETFE), and a hot press transfer step totransfer the catalyst layer 10 to the membrane as is typical withmembrane electrode assembly (MEA) fabrication.

As shown in FIG. 3, in one embodiment a subgasket 20 may be depositedover the first proton exchange membrane layer 18. In one embodiment, asubgasket material or fluid may be deposited, cast, silk-screened, ormolded over the first proton exchange membrane layer 18 and hardened,cured, or dried to form a subgasket 20. In another embodiment, thesubgasket material or fluid may be cast, molded, or applied as a filmsheet with cutouts to provide the electrochemically active area of themembrane electrode assembly. The subgasket may provide desired chemical,mechanical, and electrical properties and functions at the perimeter ofthe finished membrane electrode assembly and may also include anintegral elastomeric type seal.

In one embodiment, the depositing of the wet proton exchange membranelayer over the catalyst coated gas diffusion media layer allows themembrane electrode assembly to be fabricated using continuousprocessing, for example, roll processing. In such a process, individualsheets of membrane over a catalyst coated diffusion media layer may becut from a longer or continuous sheet. For example, the first catalystcoated gas diffusion media layer with the first proton exchange membranelayer thereon may be cut into at least two portions. The process mayeliminate the need to handle sheets of vulnerable membranes and alsoreduces alignment steps. The process may eliminate the need to providean additional substrate, for example a plastic or polymer film, for thepurpose of fabricating or conveying the proton exchange membrane.

As shown in FIG. 4A, in one embodiment a second catalyst layer 22 isapplied to a second gas diffusion media layer 24 to form a secondcatalyst coated gas diffusion media layer 26. At least a portion of thesecond catalyst layer 22 may be received in the cutout of the subgasket20. The second catalyst layer 22 may include suitable catalyticparticles, for example, metals such as platinum, platinum alloys, andother catalysts known to those skilled in the fuel cell art. The secondgas diffusion media layer 24 may be a conventional fuel cell gasdiffusion material such as nonwoven carbon fiber paper, woven carboncloth, or carbon foam, for example. The applying of the second catalystlayer 22 may include any suitable method of applying, for example,rolling, painting, or spraying. In another embodiment, an optionalsecond microporous layer 28 is applied to the second gas diffusion medialayer 24 and the second catalyst layer 22 is applied over the secondmicroporous layer 28 to form the second catalyst coated gas diffusionmedia layer 26. The microporous layer 28 may include particles and abinder. Suitable particles for the microporous layer 28 may include, butare not limited to, graphitic, graphitized, or conductive carbonparticles. Suitable binders for the microporous layer 28 may include atleast one of polytetrafluoroethylene (PTFE), polyvinylidenefluoride(PVDF), fluoroethylene propylene (FEP), or other organic or inorganichydrophobic materials.

The applying of the second microporous layer 28 may include any suitablemethod of applying, for example, rolling, painting, or spraying. Thesecond catalyst coated gas diffusion media layer 26 and the first protonexchange membrane layer 18 formed over the first catalyst coated gasdiffusion media layer 16 may be hot pressed together. After hotpressing, the second catalyst coated gas diffusion media layer 26 andthe first proton exchange membrane layer 18 formed over the firstcatalyst coated gas diffusion media layer 16 may be cut into at leasttwo portions. Alternatively, individual sheets may be cut into at leasttwo pieces before hot pressing. In one embodiment, before hot pressing,the subgaskets 20 are deposited over the first proton exchange membranelayer 18. In one embodiment, a subgasket material or fluid may bedeposited, cast, or molded over the first proton exchange membrane layer18 and hardened, cured, or dried to form a subgasket 20. In anotherembodiment, the subgasket material or fluid may be cast, molded, orapplied as a film sheet with cutouts to provide the electrochemicallyactive area of the membrane electrode assembly. The hot pressing resultsin a product 30 shown in FIG. 5. The process may eliminate the need tohandle sheets of vulnerable membranes and also reduces alignment steps.The process may eliminate the need to provide an additional substrate,for example a plastic or polymer film, for the purpose of fabricating orconveying the proton exchange membrane.

As shown in FIG. 4B, the subgasket 20 may extend past the edge of thefirst proton exchange membrane layer 18 and the first catalyst coatedgas diffusion media layer 16. In another embodiment shown in FIG. 4C, anelastomer seal 19 may be provided in contact with the subgasket 20extending past the edge of the first proton exchange membrane layer 18and the first catalyst coated gas diffusion media layer 16. Bipolarplates may be provided to receive a portion of the second catalystcoated gas diffusion media layer 26 and to receive a portion of thefirst catalyst coated gas diffusion media layer 16 and the first protonexchange membrane layer 18, so that the bipolar plates engage the seal19 to trap the reactant gases between the bipolar plates. In thealternative, the seal 19 may extend a distance sufficient to cover thesecond catalyst coated gas diffusion media layer 26 and the firstcatalyst coated gas diffusion media layer 16 and the first protonexchange membrane layer 18.

In one embodiment not shown, the subgasket 20 of product 30 shown inFIG. 5 may also extend past the edge of the first proton exchangemembrane layer 18 and the subgasket 20 may include an elastomer seal 19.

In one embodiment, the first catalyst coated gas diffusion media layer16 is the cathode gas diffusion media layer and the second catalystcoated gas diffusion media layer 26 is the anode gas diffusion medialayer. In another embodiment, the first catalyst coated gas diffusionmedia layer 16 is the anode gas diffusion media layer and the secondcatalyst coated gas diffusion media layer 26 is the cathode gasdiffusion media layer. As is known in the art, the gas diffusion medialayers 12 and 24 provide gas transport to the catalyst layers 10 and 22,respectively, and the optional microporous layers 14 and 28 arehydrophobic layers that assist in the management of water away from theproton exchange membrane(s).

In another embodiment shown in FIG. 6, a second wet proton exchangemembrane layer is deposited over the second catalyst coated diffusionmedia layer 26. The forming of the second wet proton exchange membranemay include any suitable technique, for example casting, laminating, orimbibing. The second wet proton exchange membrane may include a supportor reinforcing sheet, for example a sheet of porous material, forexample expanded polytetrafluoroethylene (ePTFE) or Teflon. In anotherembodiment, the second wet proton exchange membrane may include asupport including one of a porous material less than 30 μm thick, apaper less than 30 μm thick, polyolefins, polyethylene, polypropylene,polyesters, polyphenylene sulfide, or polymers with crystalline meltingtemperatures which do not dissolve in the coating solvents ordispersants used to imbibe an ionomer into the support material. In oneembodiment, the forming comprises casting, wherein a reinforcing sheetis evenly deposited over the catalyst layer 22 and an ionomer solutionis applied over the reinforcing sheet. The ionomer solution may be, butis not limited to, an ionomer dispersion including Nafion 1000 in 40 wt.% 1-propanol and 60 wt. % water. The ionomer solution may infiltrate orfill the pores of the reinforcing sheet. The ionomer solution may alsopenetrate at least one of the catalyst layer 22 and the microporouslayer 28. In one embodiment, the ionomer solution may be heated to flashoff the solvents and provide a dried solid polymer membrane reinforcedby the ePTFE.

In another embodiment, the forming of the second wet proton exchangemembrane comprises laminating or imbibing, wherein the reinforcing sheetis immersed in the ionomer solution to form a wet membrane, and thenthis wet reinforced membrane is evenly deposited over the catalyst layer22.

The second wet proton exchange membrane layer may be dried, for exampleunder low pressure, to form a second proton exchange membrane layer 32.

A subgasket 20 may be deposited over the first proton exchange membranelayer 18, as shown in FIG. 6. In one embodiment not shown, the subgasket20 of FIG. 6 may extend past the edge of the first proton exchangemembrane layer 18 and the subgasket 20 may include an elastomer seal 19.In another embodiment, the subgasket 20 is deposited over the secondproton exchange membrane layer 32. In one embodiment, the layers areassembled wet. In another embodiment, the first dried proton exchangemembrane layer 18 formed over the first catalyst coated gas diffusionmedia layer 16 and the second dried proton exchange membrane layer 32formed over the second catalyst coated gas diffusion media layer 26 arehot pressed together. Alternatively, individual sheets may be cut intoat least two pieces before hot pressing. The hot pressing results in theproduct 34 shown in FIG. 7. In this embodiment, a portion of the secondionically conductive membrane layer 32 overlies the subgasket 20 and aportion of the first ionically conductive proton exchange membrane layer18 underlies the subgasket 20. In another embodiment, the subgasket 20is not deposited over the first proton exchange membrane layer 18 or thesecond proton exchange membrane layer 32 before hot pressing. In oneembodiment, the product 34 may be cut into at least two portions. In oneembodiment not shown, the subgasket 20 of FIG. 7 may also extend pastthe edge of the first proton exchange membrane layer 18 and thesubgasket 20 may include an elastomer seal 19.

The following examples illustrate various embodiments of the invention.

Example 1

Carbon fiber paper available from Toray Industries, Inc. was coated witha microporous layer (containing Teflon emulsion), was sintered at 350°C., and then was coated with a dispersion of platinum on carbon (Tanaka)in a liquid ionomer solution. The multilayer coated carbon fiber paperwas heated on an 80° C. platen and an ionomer dispersion (Nafion 1000 in40 wt. % 1-propanol and 60-wt. % water) was applied using an Erichsencoater operated at 12.5-mm/sec with a Bird applicator having a 12-milcoating gap. The ionomer coating was allowed to dry for 1 hour at 80° C.The composite was then heated at 130° C. for two hours. A second pieceof catalyst-coated gas diffusion layer with a microporous layer wasplaced on top of the dried ionomer (with the catalyst facing towards theionomer film layer) with a subgasket of Kapton film between, and thecomposite was hot pressed at between 320 and 350° F. for six minutes atbetween 20 and 300 pounds per square inch pressure. After cooling toroom temperature, the resultant composite was evaluated as a membraneelectrode assembly in a fuel cell.

Example 2

Carbon fiber paper from Toray was coated with a microporous layer(containing Teflon emulsion), was sintered at 350° C., and then wascoated with a dispersion of platinum on carbon (Tanaka) in a liquidionomer solution. The multilayer was then heated at 120° C. for 30minutes. The multilayer coated carbon fiber paper was then heated withthe catalyst side up on an 80° C. platen, and expanded Teflon membrane(Donaldson Tetratex 1316) was spread evenly on top of the catalyst layerof the carbon paper support. Ionomer dispersion (Nafion 1000 in 40 wt. %1-propanol and 60-wt. % water) was then applied using an Erichsen coateroperated at 12.5-mm/sec with a Bird applicator having a 12-mil coatinggap. The ionomer coating dried at 80° C. for 1 hour and then at 130° C.for 2 hours. Then a second sheet of catalyst-coated diffusion media witha microporous layer was laid on top of the dried ionomer coated gasdiffusion layer with the catalyst layer side of the carbon fiber paperfacing towards the coated ionomer layer. The composite and was then hotpressed at between 320 and 350° F. for six minutes at between 20 and 300pounds per square inch pressure. After cooling to room temperature, theresultant composite was evaluated as a membrane electrode assembly in afuel cell.

Example 3

An expanded Teflon membrane (Donaldson Tetratex 1316) was immersed inionomer dispersion (Nafion 1000, DE2020, available from DuPont deNemours), and then the wet membrane was spread evenly on top of thecatalyst layer that had previously been coated on top of a sinteredTeflon microporous layer situated on a Toray carbon fiber paper support(O30), prepared as described in Example 1. The composite was then heatedon an 80° C. platen of an Erichsen coater. A second layer of carbonfiber diffusion media with microporous layer and catalyst layer wasapplied to the ionomer-imbibed ePTFE layer with the catalyst layerfacing towards the ionomer layer. The composite was then hot pressed atbetween 320 and 350° F. for six minutes at between 20 and 300 pounds persquare inch pressure. The resultant composite was used as a membraneelectrode assembly in a hydrogen air fuel cell.

Example 4

Multiple coatings of ionomer can be successively applied to the carbonfiber support prepared as in Examples 1 and 2, until the desired ionomermembrane thickness is realized.

Example 5

More than one layer of ionomer imbibed expanded tetrafluoroethylenemembrane from Donaldson can be applied to the ionomer layer prepared asin Example 3. The multiple layers of ePTFE are arranged such that themachine and transverse directions of the ePTFE layers are placeddiagonally to each other to improve the strength of the composite.Alternatively or additionally, one or more coatings of ionomerdispersion can be applied to the ionomer layer in Example 3 until thedesired dried ionomer membrane thickness is obtained.

Example 6

An expanded Teflon membrane (Donaldson Tetratex 1316) was immersed inionomer dispersion (Nafion 1000, DE2020, available from DuPont deNemours), and then the wet membrane was spread evenly on top of glass. Alayer of carbon fiber diffusion media was applied to the wetionomer-imbibed, expanded-polytetrafluoroethylene membrane. The carbonfiber (Toray O3O) had a platinum on carbon, catalyst layer that hadpreviously been coated on top of a sintered Teflon microporous layerthat was prepared as described in Example 1. The composite was thenheated on an 80° C. platen of an Erichsen coater. When completely dry,the ionomer and diffusion media composite was removed from the glass byimmersion in water until the composite released from the glass support.Another layer of ionomer dispersion was applied to the first ionomerlayer on the carbon fiber diffusion media using a 12-mil gap BirdApplicator, and the composite was heated on the platen of an Erichsencoater that was set at 80° C. The composite was then heated stepwisefrom 80° C. to 120° C. and then was maintained at 120° C. for fourhours. A second layer of carbon fiber diffusion media with microporouslayer and catalyst layer was then applied to the ionomer layer with thecatalyst layer facing towards the ionomer layer. The multi-layercomposite was then hot pressed at between 320 and 350° F. for sixminutes at between 20 and 300 pounds per square inch pressure. Theresultant composite was then used as a membrane electrode assembly in ahydrogen air fuel cell.

When the terms “over”, “overlying”, “overlies” or the like are usedherein with respect to the relative position of layers to each other,such shall mean that the layers are in direct contact with each other orthat another layer or layers may be interposed between the layers.

The description of the invention is merely exemplary in nature and,thus, variations thereof are not to be regarded as a departure from thespirit and scope of the invention.

1. A method comprising: providing a first catalyst coated gas diffusionmedia layer comprising a first catalyst coating over a gas diffusionmedia layer; and depositing a wet first proton exchange membrane layerover the first catalyst coated gas diffusion media layer.
 2. A method asset forth in claim 1 further comprising providing a second catalystcoated gas diffusion media layer comprising a second catalyst coatingover a gas diffusion media layer; and contacting the second catalystcoated gas diffusion media layer with the wet first proton exchangemembrane layer.
 3. A method as set forth in claim 2 further comprisinginterposing a subgasket material over the wet first proton exchangemembrane layer before contacting the second catalyst coated gasdiffusion media layer with the wet first proton exchange membrane layer.4. A method as set forth in claim 2 further comprising hot pressingtogether the wet first proton exchange membrane layer formed over thefirst catalyst coated gas diffusion media layer and the second catalystcoated gas diffusion media layer.
 5. A method as set forth in claim 3wherein the subgasket material extends past the edge of the first protonexchange membrane layer.
 6. A method as set forth in claim 5 wherein thesubgasket material further comprises an elastomer seal.
 7. A method asset forth in claim 3 further comprising hot pressing together the wetfirst proton exchange membrane layer formed over the first catalystcoated gas diffusion media layer, and the interposed subgasket material,and the second catalyst coated gas diffusion media layer.
 8. A method asset forth in claim 2 wherein at least one of the first catalyst coatedgas diffusion media layer or the second catalyst coated gas diffusionmedia layer comprises a microporous layer interposed between thecatalyst coating and the gas diffusion media layer.
 9. A method as setforth in claim 1 wherein the first proton exchange membrane layercomprises an ionomer and a support film of expandedpolytetrafluoroethylene (ePTFE), wherein the ePTFE is in intimatecontact with the catalyst coated gas diffusion media layer as theionomer is cast into the ePTFE.
 10. A method as set forth in claim 1wherein the first proton exchange membrane layer comprises an ionomerand a support film of expanded polytetrafluoroethylene (ePTFE), whereinthe ionomer is imbibed into the ePTFE prior to contacting the firstcatalyst coated gas diffusion media layer.
 11. A method as set forth inclaim 1 wherein the first proton exchange membrane layer comprises anionomer and a support, wherein the ionomer is imbibed into the supportprior to contacting the first catalyst coated gas diffusion media layer,and wherein the support comprises one of a porous material less than 30μm thick, a paper less than 30 μm thick, polyolefins, polyethylene,polypropylene, polyesters, polyphenylene sulfide, or polymers withcrystalline melting temperatures which do not dissolve in the coatingsolvents or dispersants used to imbibe the ionomer into the supportmaterial.
 12. A method as set forth in claim 1 further comprising atleast partially drying the first proton exchange membrane layer to forma dried first proton exchange membrane layer.
 13. A method as set forthin claim 1 further comprising the catalyst coating over a gas diffusionmedia layer is wet, or at least partially wet, immediately beforedepositing the first proton exchange membrane layer.
 14. A method as setforth in claim 2 wherein the second catalyst coating over a gasdiffusion media layer is at least partially wet immediately beforecontacting the second catalyst coated gas diffusion media layer with thefirst proton exchange membrane layer.
 15. A method as set forth in claim2 further comprising, before the contacting, cutting into at least twoportions the second catalyst coated gas diffusion media layer and thefirst proton exchange membrane layer formed over the first catalystcoated gas diffusion media layer.
 16. A method as set forth in claim 4further comprising, before the hot pressing, cutting into at least twoportions the first proton exchange membrane layer formed over the firstcatalyst coated gas diffusion media layer and the second catalyst coatedgas diffusion media layer.
 17. A method as set forth in claim 4 furthercomprising, after the hot pressing, cutting into at least two portionsthe first proton exchange membrane layer formed over the first catalystcoated gas diffusion media layer and the second catalyst coated gasdiffusion media layer.
 18. A method comprising: providing a firstcatalyst coated gas diffusion media layer and a second catalyst coatedgas diffusion media layer; depositing a wet first proton exchangemembrane layer over the first catalyst coated gas diffusion media layerand drying the first proton exchange membrane layer to form a firstproton exchange membrane layer; depositing a wet second proton exchangemembrane layer over the second catalyst coated gas diffusion media layerand drying the second proton exchange membrane layer to form a secondproton exchange membrane layer; and hot pressing the first protonexchange membrane layer formed over the first catalyst coated gasdiffusion media layer and the second proton exchange membrane layerformed over the second catalyst coated gas diffusion media layertogether.
 19. A method as set forth in claim 18 further comprising,before the hot pressing, interposing a subgasket between the firstproton exchange membrane layer and the second proton exchange membranelayer.
 20. A method as set forth in claim 19 wherein the subgasketextends past the edge of the first proton exchange membrane layer.
 21. Amethod as set forth in claim 19 wherein the subgasket further comprisesan elastomer seal.
 22. A method as set forth in claim 18 wherein atleast one of the first or second proton exchange membrane layercomprises an ionomer and a support film of expandedpolytetrafluoroethylene (ePTFE), wherein the ePTFE is in intimatecontact with the catalyst coated gas diffusion media layer as theionomer is cast into the ePTFE.
 23. A method as set forth in claim 18wherein at least one of the first or second proton exchange membranelayer comprises an ionomer and a support, wherein the ionomer is imbibedinto the support prior to contacting the first catalyst coated gasdiffusion media layer, and wherein the support comprises one of a porousmaterial less than 30 μm thick, a paper less than 30 μm thick,polyolefins, polyethylene, polypropylene, polyesters, polyphenylenesulfide, or polymers with crystalline melting temperatures which do notdissolve in the coating solvents or dispersants used to imbibe theionomer into the support material.
 24. A method as set forth in claim 18wherein at least one of the first or second proton exchange membranelayer comprises an ionomer and a support film of expandedpolytetrafluoroethylene (ePTFE), wherein the ionomer is imbibed into theePTFE prior to contacting the first catalyst coated gas diffusion medialayer.
 25. A method as set forth in claim 18 wherein at least one of thefirst proton exchange membrane layer or the second proton exchangemembrane layer is at least partially wet immediately before the hotpressing.
 26. A method as set forth in claim 18 wherein at least one ofthe first catalyst coated gas diffusion media layer or the secondcatalyst coated gas diffusion media layer comprises an at leastpartially wet catalyst coating layer immediately before depositing theproton exchange membrane layer.
 27. A method as set forth in claim 18wherein at least one of the first catalyst coated gas diffusion medialayer or the second catalyst coated gas diffusion media layer comprisesa microporous layer interposed between the catalyst coating and the gasdiffusion media layer.
 28. A method as set forth in claim 18 furthercomprising cutting into at least two portions at least one of the firstcatalyst coated gas diffusion media layer with the first proton exchangemembrane layer thereon or the second catalyst coated gas diffusion medialayer with the second proton exchange membrane layer thereon.
 29. Aproduct comprising: a first gas diffusion media layer and a firstcatalyst layer overlying the first gas diffusion media layer; a secondgas diffusion media layer and a second catalyst layer overlying thesecond gas diffusion media layer; a proton exchange membrane layeroverlying at least one of the first catalyst layer or the secondcatalyst layer; and a subgasket interposed between the first catalystlayer and the second catalyst layer and wherein a portion of the protonexchange membrane layer overlies the subgasket and a portion of theproton exchange membrane layer underlies the subgasket.
 30. A product asset forth in claim 29 wherein the first catalyst layer is an anodecatalyst layer and the second catalyst layer is a cathode catalystlayer.
 31. A product as set forth in claim 29 wherein each of the firstcatalyst layer and the second catalyst layer comprise at least one ofplatinum or platinum alloys.
 32. A product as set forth in claim 29wherein the proton exchange membrane layer comprises an ionomer and asupport film of expanded polytetrafluoroethylene (ePTFE), wherein theionomer at least fills the total porous structure of the ePTFE.
 33. Aproduct as set forth in claim 29 wherein the proton exchange membranelayer comprises an ionomer and a support, wherein the ionomer is imbibedinto the support prior to contacting the first catalyst coated gasdiffusion media layer, and wherein the support comprises one of a porousmaterial less than 30 μm thick, a paper less than 30 μm thick,polyolefins, polyethylene, polypropylene, polyesters, polyphenylenesulfide, or polymers with crystalline melting temperatures which do notdissolve in the coating solvents or dispersants used to imbibe theionomer into the support material.
 34. A product as set forth in claim29 wherein each of the first gas diffusion media layer and the secondgas diffusion media layer comprise at least one of nonwoven carbon fiberpaper, woven carbon cloth, or carbon foam.
 35. A product as set forth inclaim 29 wherein the subgasket extends past the edge of the protonexchange membrane layer.
 36. A product as set forth in claim 35 whereinthe subgasket further comprises an elastomer seal.
 37. A product as setforth in claim 29 further comprising a microporous layer overlying atleast one of the first gas diffusion media layer or the second gasdiffusion media layer.
 38. A product as set forth in claim 37 whereinthe microporous layer comprises a binder and particles.
 39. A product asset forth in claim 38 wherein the binder comprises at least one ofpolytetrafluoroethylene (PTFE), polyvinylidenefluoride (PVDF), orfluoroethylene propylene (FEP).
 40. A product as set forth in claim 38wherein the particles comprise at least one of graphitic carbonparticles, graphitized carbon particles, or conductive carbon particles.